Learn how to use the pentool in Photoshop

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Today I was on what Google Translate tells me is "tet" in English, but I don't know.
For this week me and the rest of our class will be visiting companies and see how they work.
(eXore is an electronics store and lifting boxes xD)
I'm on a advertising agency with a really cool guy who knows everything about Adobe software.
He told me that he was going to show me the one tool that will make Photoshop a better program.
I learned the basics of how to use it I just think it's awesome, that's why I'm going to try to learn you what he learned me.

Sorry for the long intro, let's get started

The pentool can be found here
 
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