It is possible, is it plausible?
Obviously, the United Nations, and practically every single country in the world, is aware that a nuclear war would most likely result in a nuclear holocaust, or perhaps just causing a large portion of the earth's land mass inhabitable. So the only likely scenario where a Nuclear Holocaust could happen is when hostile extremists gain access to WMDs.
I'm interested in your opinion. Of course, United Nations is well prepared for situations such as these, but I want to hear the arguments and counterarguments you guys may have for a nuclear war of sorts.
PS: I said "most likely cause a nuclear holocaust" because as of right now only major powers have wmds. Those major powers have stronger alliances with some than they do with others.